
Onion-like nanoparticles found in aircraft exhaust
—Revealed by high-resolution transmission electron microscopy—
The related research paper has been published in ACS ES&T Air, a journal in the field of atmospheric sciences, by the American Chemical Society (ACS), on 8 April, 2025.
1. Background and purpose of the study
Aircraft emit nanoparticles (<50nm, Note 1 in diameter) into the atmosphere, from the ground to the upper troposphere. Studies in Europe, the U.S., and Japan have reported high concentrations of particles in and around airports Ref 1, and there is worldwide concern regarding the effects on human health. The atmospheric heating effects by contrails generated from aircraft exhaust particles are also known, and research is being conducted to assess their potential impacts on climate. Particle number emissions from turbofan jet engines, which are commonly used in civil aviation, are generally dominated by volatile particles (sulfate or organics) rather than non-volatile particles (mostly soot). However, the emission and formation mechanisms of the volatile particles are not well understood. Our research team investigated the physicochemical properties of aircraft exhaust nanoparticles (volatile and non-volatile) to obtain information on the emission and formation mechanisms of volatile particles.
2. Methods
We measured the morphology and internal (microphysical) structure of exhaust particles at the engine exit and 15m downstream of commercial turbofan jet engines at a test facility in Zurich Airport, Switzerland. The morphology and internal structure of the particles were observed by high-resolution transmission electron microscopy (HRTEM) using bulk particulate samples collected on thin films.
3. Results and discussion
Four types of aircraft engine exhaust particles with different internal structures were observed (Fig. 1). Type (a) represented turbostratic particles with scattering-layered graphene-like structures Note 2 and were considered typical for soot (non-volatile particles). Type (b) consisted of onion-like particles with partial graphite-like structures, which are well-ordered graphene-like spherical multilayers. Type (c) particles were amorphous (non-crystalline), and type (d) were trace amorphous particles (images are thin and non-crystalline). Before this study, onion-like particles were not identified in the combustion exhaust or atmosphere. Although graphitic soot emitted from aircraft has been studied for many years, three other types of particles were identified for the first time in this study.

The number fraction of turbostratic (soot) particles was high at the engine exit and lower than 1% at 15 m downstream (Fig. 1). Fifteen meters downstream, the remaining fraction was dominated by onion-like, amorphous, and trace amorphous particles. These three types of particles were mostly single (non-agglomerated, Note 3) spherical particles with diameters of 10–20nm. Further analysis suggested that these three types of particles are volatile particles formed via nucleation and condensation downstream of the engine and mainly consist of organic compounds originating from the lubrication oil.
4. Outlook
These unique internal structures may affect the physicochemical properties of the particles, including volatility, surface reactivity, and solubility, and potentially affect the interaction of the particles with the human respiratory tract. Our research team found that aircraft emit onion-like, amorphous, and trace amorphous particles in addition to soot particles. However, there are many questions regarding the physicochemical characteristics, origin, and formation mechanism of onion-like particles, and whether they are similar in nature to soot or volatile organic particles, such as oil mist. The onion-like particles may have different dynamics in the atmosphere and body compared with other particles; therefore, further research is needed to understand their climate and health implications.
In the field of nanomaterials, onion-like particles are synthesized by applying high energy to soot, among other methods. The formation mechanism of onion-like particles from aircraft engines is scientifically interesting and has potential implications in materials and other fields.
5. Annotations
Note 1.nm: Nanometer. One nanometer is one-millionth of a millimeter (mm). Particle diameter (size) of 50nm is about 1/1000th the size of cedar pollen (about 30μm in diameter). One micrometer is 1/1000th of a millimeter.
Note 2.Graphene: A thin sheet of material with a crystalline structure of carbon atoms linked together in a hexagonal shape.
Note 3.Agglomeration: Adhesion and coalescence of particles to form large aggregates. Soot particles produced by incomplete combustion often form large agglomerates that are shaped like grape bunches.
Ref 1.Fushimi, A.; Saitoh, K.; Fujitani, Y.; Takegawa, N. Identification of jet lubrication oil as a major component of aircraft exhaust nanoparticles. Atmos. Chem. Phys. 2019, 19, 6389−6399.
https://doi.org/10.5194/acp-19-6389-2019 (Connect to an external site)
6. Research grants
This work was supported by the Environment Research and Technology Development Fund (JPMEERF20205004, JPMEERF20245005) of the Environmental Restoration and Conservation Agency provided by the Ministry of the Environment of Japan, the Scientific Exchanges grant from the Swiss National Science Foundation (IZSEZ0_198063), and the Swiss Federal Office of Civil Aviation (FOCA) projects (AGEAIR SFLV 2017-030 and AGEAIR 2 SFLV 2018-048).
7. Publication
【Title】
Unique Microphysical Structures of Ultrafine Particles Emitted from Turbofan Jet Engines
【Authors】
Akihiro Fushimi 1, Yuji Fujitani 1, Lukas Durdina 2, Julien G. Anet 2, Curdin Spirig 2, Jacinta Edebeli 2, Hiromu Sakurai 3, Yoshiko Murashima 3, Katsumi Saitoh 4,1, Nobuyuki Takegawa 5
【Affiliations】
1 National Institute for Environmental Studies, Japan, 2 Zurich University of Applied Sciences, Switzerland, 3 National Institute of Advanced Industrial Science and Technology, Japan, 4 Environmental Science Analysis and Research Laboratory, Japan, 5 Tokyo Metropolitan University, Japan.
【掲載誌】ACS ES&T Air
【DOI】10.1021/acsestair.4c00309 (Connect to an external site)
8. Press Release Presenters
Akihiro Fushimi, Ph. D., Chief Senior Researcher
Earth System Division
National Institute for Environmental Studies, Japan
Yuji Fujitani, Ph. D., Chief Senior Researcher
Health and Environmental Risk Division
National Institute for Environmental Studies, Japan
Lukas Durdina, Ph.D., Senior Scientist
Julien G. Anet, Ph.D., Head of the Meteorology, Environment and Aviation research unit
Curdin Spirig, Scientist
Jacinta Edebeli, Ph.D., Scientist
Centre for Aviation, Zurich University of Applied Sciences, Switzerland
Nobuyuki Takegawa, Ph. D., Professor
Department of Chemistry, Graduate School of Science
Tokyo Metropolitan University, Japan
9. Contacts
【Contact for the research】
Akihiro Fushimi, Ph.D., Chief Senior Researcher
Earth System Division
National Institute for Environmental Studies
【Contact for the press release】
Public Relations Office, Planning Division
National Institute for Environmental Studies
Email: kouhou0 (please append ‘@nies.go.jp’ to complete the email address)
- What's New
- What's New 2025
- What's New 2024
- What's New 2023
- What's New 2022
- What's New 2021
- What's New 2020
- What's New 2019
- What's New 2018
- What's New 2017
- What's New 2016
- What's New 2015
- What's New 2014
- What's New 2013
- What's New 2012
- What's New 2011
- What's New 2010
- What's New 2009
- What's New 2008
- What's New 2007
- What's New 2006
- What's New 2005
- What's New 2004
- What's New 2003
- What's New 2002
- Event Information
- Visit NIES