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The World of Protozoa, Rotifera, Nematoda and Oligochaeta

Ref ID : 2012

H.R. von Gunten and Ch. Lienert; Decreased metal concentrations in ground water caused by controls of phosphate emissions. Nature 364:220-222, 1993

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A new generation of phosphate-eliminating sewage treatment plants and the recent prohibition of phosphates in detergents have considerably reduced the concentrations of phosphate in surface waters. But there has been concern that replacing phosphate in detergents with complexing agents might cause increased mobilization of heavy metals, and consequent pollution of ground waters. Here we present a twelve-year analysis of phosphate, manganese and cadmium in the river Glatt, Switzerland, and in an adjacent aquifer which is infiltrated by the river water. Together with a reduction of phosphate concentrations in both river and ground water over the study period, we find lower groundwater concentrations of manganese and cadmium. We postulate that lower phosphate levels have decreased the amount of oxidizable organic carbon in the river bed, and hence have created less reducing conditions in the infiltrating water. This in turn has resulted in decreased reductive dissolution of manganese and cadmium in the ground water. It thus appears that eliminating phosphate has led to an unexpected improvement in drinking water quality with respect to heavy metals.